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Q.

Which of the following equations is a balanced one ?

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a

5 BiO3- + 22H+ + Mn2+   5Bi3+ + 7H2O + MnO4-

b

5 BiO3- + 14H+ + 2Mn2+   5Bi3+ + 7H2O + 2MnO4-

c

2 BiO3- + 14H+ + Mn2+   2Bi3+ + 2H2O + MnO4-

d

6 BiO3- + 12H+ + 3Mn2+   6Bi3+ + 6H2O + 3MnO4-

answer is B.

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Detailed Solution

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Bi+5O3- + Mn+2  Bi+3 + Mn+7O4-

Change in oxidation state of ‘Bi’ = 2

Change in oxidation state of ‘Mn’ = 5

According to oxidation number method , (change in oxidation states are cross multiplied)

5 BiO3- + 2Mn2+   5Bi3+ + 2MnO4-

Balance  H and O atoms

5 BiO3- + 14H+ + 2Mn2+   5Bi3+ + 7H2O + 2MnO4-

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