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Q.

Which of the following expressions correctly represents the equivalent conductance at infinite dilution. Given that λ0Al+3 and λ0SO42- are the equivalent conductances at infinite dilution of respective ions.

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a

2λAl +30+3λSO420

b

λAl +30+λSO420

c

λAl +30+λSO420×6

d

13λAl +30+12λSO420

answer is B.

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Detailed Solution

λM0Al2(SO4)32×λM0Al+3+3λM0(SO4)3

λM0Al2(SO4)3=λeq0Al2(SO4)3×nfactorλeq0Al2(SO4)3=2×λM0Al+3+3λM0(SO42)6=66×λeq0Al+3+66λeq0(SO42)λeq0Al2(SO4)3=λeq0Al+3+λeq0(SO42)

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