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Q.

Which of the following factors is not relevant for roasting sulphide ores to oxides and not subjecting the sulphide ores to carbon reduction directly?

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a

CO2 is more volatile than CS2

b

Metal sulphides are thermodynamically more stable than CS2

c

CO2 is thermodynamically more stable than CS2

d

Metal sulphides are less stable than the corresponding oxides

answer is D.

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Detailed Solution

Metal sulphides are more stable than corresponding oxides and that is why it is more difficult to extract metal from sulphide ore. To make the extraction easy and economical, first these sulphides are converted into their corresponding oxides and from these oxides metal is easily extracted by reducing them with carbon. 

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