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Q.

Which of the following factors may be regarded as the main cause of lanthanide contraction?

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a

Poorer shielding of 5d electrons by 4f electrons

b

Greater shielding of 5d electrons by 4f electrons

c

 Effective shielding of one of 4f electrons by another in the subshell

d

Poor shielding of one of 4f electrons by another in the subshell

answer is C.

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Detailed Solution

The lanthanide contraction is due to the fact that 4 f electrons shield each other from the nuclear charge poorly. As more 4f electrons are added, the effective nuclear charge felt by each of them increases. As a consequence, the whole 4f electron shell contracts on passing across the lanthanides.

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