Q.

Which of the following facts regarding ClF3 is correct?

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a

There are two lone pair of electrons occupying equatorial positions

b

The angles FClF are 120°

c

There is no lone pair of electrons around Cl

d

All the three ClF bond has the same length

answer is D.

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Detailed Solution

The structure of ClF3 is 

Question Image

The FClF bond angles is 87°. It is less than 90° because of lone-pair-bond pair electron repulsions. The two bond lengths are 169.8 pm (axial bond) and 159.8 pm (equatorial bond). 

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