Q.

Which of the following form an ideal solution? 
I.  Chloroethane & bromoethane  
II. Benzene & toluene
III. n-Hexane & n-Heptane
IV. Phenol & aniline

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a

 I & IV Only

b

 I,II &III Only

c

 I & II Only

d

II,III&IV Only

answer is B.

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Detailed Solution

An ideal solution obeys Raoult's law at all temperatures and pressures.
The solute-solute and the solvent-solvent interactions are almost similar to solute-solvent interactions. No association or dissociation takes place. It does not form azeotrope mixture.

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