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Q.

Which of the following forms maximum number of isomers ?

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a

Co(en)2Cl2+

b

CoNH35Cl2+

c

IrPR32H(CO)2+

d

RuNH34Cl2+

answer is A.

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Detailed Solution

  (a)Co(en)2Cl2+M(AA)2b2nt Total structural isomers =0 Total geometrical isomers =2 Total optical isomers =3 Total stereoisomers =3
(b) CoNH35Cl2+Ma5b±n
Total stmctural isomers = 0
Total geometrical isomers = 0
Total optical isomers = 0
Total stereoisomers = 0
 (c)  IrPR3H(CO)2+Ma2bcn± (Square planer) 
Total structural isomers = 0
Total geometrical isomers = 2
Total oPtical isomers =0
Total stereoisomers = 2
 (d)  RuNH34Cl2+Ma4b2±n
Total strucnrral isomers = 0
Total geometrical isomers =2
Total optical isomers = 0
Total stereoisomers = 2

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