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Q.

Which of the following formula represents a first order reaction

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a

k=2.303tlog[A]0[A]t

b

k=1t.xa(ax)

c

k=2.303tlogaax

d

k=2.303tlogax

answer is C.

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Detailed Solution

Consider the reaction AProducts

Let a  is the concentration of A at initial.

After time t, the concentration of A

Becomes (ax) and x has been changed into products.

 The rate reaction after time ‘t’ is given by

          dxdt=k(ax)

        dx(ax)=kdt

Upon integration of above equation, will get

     dx(ax)=kdt

loge(ax)=kt+ceqn(1)

Where c is integration constant

When        t=0       x=0

  C=logea

Putting the value of c in equation (1), we will get

logealoge(ax)=kt

logea(ax)=kt

k=2.303tlog10a(ax)=2.303tlog10[A]0[A]t

Here , k is rate constant , [A]0=aand[A]t=ax

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