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Q.

Which of the following gives two isomers of 3° alcohol, when treated with phenyl magnesium bromide ?

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a

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b

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c

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d

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answer is B.

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Detailed Solution

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The correct answer for the question "Which of the following gives two isomers of 3° alcohol, when treated with phenyl magnesium bromide?" is:

Option b.

Explanation:

  • Phenyl magnesium bromide (C₆H₅MgBr) reacts with ketones to form tertiary alcohols.
  • Option b shows a structure where two different substituents are present on the carbonyl group, making it possible for two isomers to form when phenyl magnesium bromide reacts with the ketone.
  • The different locations for the phenyl group to add lead to the formation of two possible tertiary alcohol isomers.
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Which of the following gives two isomers of 3° alcohol, when treated with phenyl magnesium bromide ?