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Q.

Which of the following graphs are correct for a first order reaction?

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a

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b

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c

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d

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answer is A.

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Detailed Solution

For the first order reaction,
k=2.303tlog [R]0[R]kt2.303=log [R]0[R]          
    log RoR=k2.303x t+0                                              y =          m           x +c 
Correct plot of log RoR can be represented by (d)
where, slope = k2.303
The time taken for any fraction of the reaction to complete is independent of the initial concentration.
Let, us consider it for half of the reaction to complete.
              t=2303klog aax
For half-life (t)=t1/2 and x=a2
                   t1/2=2.303klog aaa2
           t1/2=2.303klog 2
    Half-life time  t1/2=0.693k
t12is independent of initial concentration. Hence, correct plot of t12 and Rocan be represented by option (a).

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Which of the following graphs are correct for a first order reaction?