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Q.

Which of the following graphs represent a first order reaction ( a= initial concentration of reactant, x= concentration of reactant consumed, t= time)

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a

a,b,d

b

c,d

c

a,b,c

d

a,b

answer is D.

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Detailed Solution

For a first order reaction
 Rate =-ΔA]Δl=k[A]
It is a straight line plot with negative slope when concentration of reactant is considered as in (i) and half-life for first order is independent from concentration, as in plot (ii). 

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