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Q.

Which of the following group is meta directing and ring deactivating

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a

-OH

b

 -Cl

c

-NO2

d

-Br

answer is C.

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Detailed Solution

 Looking at the resonance structures reveals that the positive charge concentrates at the ortho-para positions because NO2 is an electron withdrawing group. These locations are thereby rendered inactive with respect to electrophilic aromatic substitution. 

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