Q.

Which of the following has a maximum number of hyperconjugation structures?

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a

isopropyl carbonium ion

b

tertiary butyl carbonium ion

c

n-propyl carbonium ion

d

Benzyl carbonium ion

answer is B.

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Detailed Solution

For (A), it is a secondary carbonium ion and has six sp3 hybridized hydrogen, thus six hyper-conjugated structures are possible.
For (B), it has nine sp3 hybridized hydrogen, thus nine hyper-conjugated structures are possible.Question Image
For (C), has two sp3 hybridized hydrogen, thus two hyper-conjugated structures are possible.
For (D), has zero sp3 hybridized hydrogen, thus zero hyper-conjugated structures are possible.
 

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