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Q.

Which of the following has a planar structure ?

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a

NH4+

b

BF4-

c

XeF4

d

SCl4

answer is C.

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Detailed Solution

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In  XeF4 the ‘Xe’ atom is sp3d2 hybridised, which contains two lone pairs and four bond pairs. 

Therefore the shape of the  XeF4 molecule is square planar.

In NH4+ , central atom(N) is sp3 hybridized and the shape is tetrahedral

In SCl4(1l.p+4b.p), Sulphur is sp3d hybridized and the shape is see-saw.

In BF4-, Boron is sp3 hybridized and the shape is tetrahedral.

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