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Q.

Which of the following has a square planar geometry?
 

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a

 [FeCl4]2

b

 [NiCl4]2

 

c

 [PdCl4]2

d

 [CoCl4]2

answer is C.

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Detailed Solution

It is given to find out the compound which has a square planar geometry. 

The nature of the ligand affects the hybridization of the compound which in turn affects the geometry. 

Explanation

In  [PdCl4]2, the oxidation state of Pt is +2. So, the electronic configuration is 5d8
Six electrons are paired and two remain unpaired in the ground state. 

Cl- is a weak ligand, yet it causes electron pairing in 5d, opening up one 5d orbital. This results in dsp2 hybridization and square planar geometry.

Hence the correct answer is C) [PdCl4]2

 

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