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Q.

Which of the following has an optical isomer?

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a

${[Co {({NH}_{3})}_{3} Cl]}^{+}$

b

${[Co {(H_{2} O)}_{4} (en)]}^{3 +}$

c

${[Co (en) {({NH}_{3})}_{2}]}^{2 +}$

d

${[Co (en)_{2} {({NH}_{3})}_{2}]}^{3 +}$

answer is C.

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Detailed Solution

$[Co {({en}_{2} {({NH}_{3})}_{2}]}^{3 +}$ has an optical isomer.

It is a $[M (AA)_{2} X_{2}]$ octahedral complex, where AA is a bidentate ligand.

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Hence, option C is correct.

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Which of the following has an optical isomer?