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Q.

Which of the following has higher IP1 ?

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a

Oxygen

b

Sulphur

c

Selenium

d

Tellurium

answer is A.

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Detailed Solution

Electronic configuration of Oxygen =[He]2s22p4

Electronic configuration of Sulphur =[Ne]3s23p43d0

Electronic configuration of Selenium =[Kr]4s24p44d0

Electronic configuration of Tellurium =[Xe]5s25p46d0

Ionisation potential decreases with increase in the number of shells since it becomes easier to lose an electron due to less attraction between nucleus and outermost electron.

Thus, oxygen has higher IP1.

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