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Q.

Which of the following has least freezing point?

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a

1% sucrose

b

1% NaCl

c

1% CaCl2

d

1% glucose

answer is C.

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Detailed Solution

Depression in freezing point is a colligative property (i.e. depends only upon the number of particles of solutes). Thus, the compound which produces maximum number of
ions will have the least freezing point.
Concentration is same
                  Sucrose No ions NaCl     Na+ +Cl-                     Two ions
                 CaCl2     Ca2+2Cl-                    Three ions
                Glucose  No ions 
Thus, 1%  CaCl2 will have the least freezing point.

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