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Q.

Which of the following has maximum angular volume of orbital containing lone pair?

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a

${NF}_{3}$

b

${NH}_{3}$

c

${PH}_{3}$

d

${PCl}_{3}$

answer is C.

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Detailed Solution

${PH}_{3}$ has lone pair in s-orbital.

Hence, the correct answer is ${PH}_{3}$ .

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Which of the following has maximum angular volume of orbital containing lone pair?