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Which of the following has maximum bond angle of $X \hat{P} X$ ?

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${POF}_{3}$

${POCl}_{3}$

${POBr}_{3}$

${POI}_{3}$

answer is D.

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Detailed Solution

The degree of hybridization of the core atom affects the bond angle. The bond angle will be greater the more electronegative the core atom is. The bond angle has a direct relationship with electronegativity.

Hence, the correct answer is ${POI}_{3}$ .

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