Q.

Which of the following has the highest bond dissociation energy?
 

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a

CH3-Cl

 

b

CH3-I

c

 CH3-Br

d

CH3-F 

answer is A.

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Detailed Solution

There is a significant difference in electronegativity between the C and X atoms because of the high electronegativity of the halide ion (denoted by X-). As a result, the C-X bond has a substantial polar character and is not entirely covalent. As we proceed from fluorine to iodine in the group, the C-X bond length rises as the size of the halide ion grows down the group. 

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