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Q.

Which of the following has the highest tendency to give the following reaction.

Mg+mediumaqueousMaq.+

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a

Na

b

Li

c

Rb

d

K

answer is B.

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Detailed Solution

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Mg+mediumaqueousMaq.+

Lig+  has the highest tendency to give the Liaq.+
Reason:

Li+ ion is smaller in size. Hence, it possesses greater nuclear charge So attraction of water molecules by Li+ ion increases. Therefore, degree of hydration increases, and hence, hydration energy increases. It is an Exothermic process
NOTE:
The amount of energy released during the hydration of 1 mole of ions is called hydration energy.
Stability of  Maq+  hydraction energy

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