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Q.

Which of the following has the longest C-O bond length? (Free C-O bond length in CO is 1.128 Å)

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a

 [Mn(CO)6]+

b

 Ni(CO)4

c

[Fe(CO)4]2

d

 [Co(CO)4]

answer is A.

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Detailed Solution

[Fe(CO)4]2has the longest C–O bond. Because the complex metal atom has the most negative charge, it will exhibit the most synergistic bonding, causing the C-O bond length to be at its maximum.  

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