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Q.

Which of the following have distorted octahedral structure?

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a

${XeF}_{6}$

b

${SiF}_{6}^{2 -}$

c

${SF}_{6}$

d

${PF}_{6}^{⊖}$

answer is D.

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Detailed Solution

${AB}_{6} E type (: {XeF}_{6}) have s p^{3} d^{3}$ hybrid orbitals with pentagonal bipyramidal geometry where as shape of molecule is

distorted Octahedral structure.

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