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Q.

Which of the folloWing hydrated salts will not become anhydrous on heating?

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a

MgCl26H2O

b

FeCl36H2O

c

AlCl36H2O

d

CoCl26H2O

answer is A, B, C.

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Detailed Solution

MgCl2, AlCl3, and SnCl2 are the chemical formulas for water. MgCl26H2O,AlCl36H2O, and SnCl22H2Ocannot be heated only to form anhydrous chloride. As, the ions  Mg2+,Al3+and Sn2+ have more polarisation power.

MgCl26H2OMgO+2HCl+5H2

2AlCl36H2OAl2O3+6HCl+9H2O

SnCl22H2OSnO+2HCl+H2O.

So, option A, B and C are correct.

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Which of the folloWing hydrated salts will not become anhydrous on heating?