Q.

Which of the following information is correct with respect to group 15 elements and their compounds

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a

Colourless gas is produced when concentrated HNO3 reacts with Zn and Cu

b

White phosphorous on reaction with alkali gives of hypo phosphorous acid where as red phosphorous on heating with alkali gives of hypo phosphoric acid

c

Phosphorous acid on heating disproportionate to give phosphoric acid and hypo phosphorous acid

d

N – N bond length in N2O3 and N2O4 are almost comparable

answer is D.

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Detailed Solution

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(A) NO2 gas will be produced
(B) Bond length are different
(C)  H3PO3ΔH3PO4+PH3
(D) Theory

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