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Q.

Which of the following ion pairs are incorrect for the given substance?

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a

PBr5(s):PBr4+PBr6

b

N2O4(s):NO2+NO2

c

XeF6(s):XeF5+XeF7

d

Common salt: Na+[Cl]

answer is A, C, B.

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Detailed Solution

Trigonal bipyramidal shape is shared by PCl5 and PBr5. This construction lacks regularity and stability. In order to form more sturdy octahedral and tetrahedral structures, PCl5 fragments. which have more stability than trigonal bipyramidal.

PCl5PCl6PCl4+

In contrast, as PBr5 fragments, a stable tetrahedral structure

PBr4+[Br]PCl5PBr4+[Br]

Due to the size of Br atoms and the difficulty of fitting six Br atoms around a smaller Br atom, this splitting differs fromPCl5 splitting.

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