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Q.

Which of the following ions if reduced under standard conditions will have negative reduction potential?

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a

Cu2+

b

Zn2+

c

Au3+

d

Hg22+

answer is B.

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Detailed Solution

Zn2+ is less readily reduced than H+ whereas Cu2+,Au3+ and Hg22+ are more readily reduced. Thus, Zn2+Zn has negative reduction potential.

The term "reduction potential" (Eo) refers to a chemical species' propensity to undergo reduction by obtaining an electron. It is used in electrochemistry to characterize hydrogen, which typically has a reduction potential of zero [24].

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