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Q.

Which of the following is a correct statement ?

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a

Aq. solutions of Cu+ and Zn2+ are colour less

b

Aq. solutions of Cu2+ and Zn2+ are colour less

c

Aqueous solutions of Fe3+ is green in colour

d

Aqueous solutions of MnO4 is colourless

answer is A.

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Detailed Solution

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Configuration of Cu+2−[Ar]3d9Zn+2−[Ar]3d10

Copper has an unpaired electron which acts as a F center and allows electron transition in visible region importing color while Zn+2 is having no unpaired electrons hence colorless.

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