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Q.

Which of the following is a polar molecule?

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a

BF3

b

SF4

c

SiF4

d

XeF4

answer is B.

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Detailed Solution

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Molecule having defi nite dipole moment is unsymmetrical and polar.
Symmetrical molecules are having zero dipole moment and is non-polar in nature.
SF4
4 bond pair
1 lone pair
Unsymmetrical μ0
Polar molecule
(1) SiF4       4 bpe-
                      Tetrahedral sp3
                      Non polar (μ=0)
(2) XeF4       4bpe-
                        2 lpe-
                        Square planar sp3d2
                        Non polar (μ=0)
(3) BF3          3 bpe
                        sp2
                        Trigonal planar (μ=0)

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