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Q.

Which of the following is a wrong order with respect to the property mentioned against each?

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a

(NO)>(NO)>NO+) ( Bond length)

b

H2>H2+>He2+ (Bond energy)

c

O22>O2>O2++ (paramagnetic moment)

d

NO2+>NO2>NO2 (Bond angle)

answer is C.

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Detailed Solution

The order O22>O2>O2++ [ for paramagnetic moment] is wrong.

O2 and O2 are paramagnetic while O22  is diamagnetic.

If unpaired electrons are present in an ion/molecule, then it is paramagnetic. If all electrons are paired, then the ion/molecule is diamagnetic

The value of dipole moment of these molecules can be given as,

O22 has  μ=0,O2 has 2.83BM,O22+ has μ=0.

Hence correct option is C.

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