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Which of the following is a wrong statement?

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The electrophile in sulphonation is $H_{2} S O_{4}$

In the nitration of toluene by electrophilic substitution the electrophile is nitronium ion

Reaction of benzene with chlorine in the presence of sunlight is an addition reaction

In Friedel-crafts reaction of benzene with an acid chloride the electrophile reagent is $R C O^{+}$

answer is A.

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Detailed Solution

(A) In sulfonation of benzene SO₃ acts as an electrophile and accepts a pair of pi electrons from Benzene

H₂SO₄+ H₂SO₄ $⥪$ H₃O⁺ + SO₃ +HSO^-₄

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