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Q.

Which of the following is an allylic halide?

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a

CH2=CHX

b

C6H5Cl

c

CH3CH2X

d

CH2=CH-CH2X

answer is B.

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Detailed Solution

Halides known as allylic halides are those in which a halogen atom is joined to a carbon atom that has undergone sp3 hybridization next to a carbon-carbon double bond (C=C). Allylic halides have the following general chemical structure:

CH2=CH-CH2-X

X here can be any halogen atom.
Let's now sketch the composition of each compound to identify the allylic halide. - 3-bromo -2-methylpropene

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- 3-bromobut-1-ene:

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- 3-bromopent-2-ene

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 - 4-bromobut-1-ene

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The structures of the aforementioned compounds show that bromine is joined to the sp3 hybridised carbon atom, which is adjacent to the carbon-carbon double bond or sp2 hybridised carbon, in 3-bromo-2-methylpropene and 3-bromobut-1-ene. Thus, the allylic halides 3-bromo-2-methylpropene and 3-bromobut-1-ene are both present.

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Which of the following is an allylic halide?