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Q.

 Which of the following is an example of electrophilic substitution?

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a

Diazo coupling

b

Diazotization 

c

Sandmayer reaction

d

Action of KCN on ArN2Cl

answer is B.

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Detailed Solution

 In diazo coupling, ArN2Cl reacts with phenol to form a diazo coupling product. The ArN2Cl acts as an electrophile and the OH group in phenol is an electron donating group so it favors the electrophilic substitution reaction. Hence, the diazo coupling reaction is an example of electrophilic substitution.

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