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Q.

Which of the following is/are correct statement(s)? 

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a

The difference in angular momentum associated with the electron present in consecutive orbits of unipositive helium ion is h2π

b

Energy difference between any two energy levels of electron in hydrogen atom changes if potential energy of electron is assigned non-zero value at infinite distance from the nucleus

c

Wavelength of emission spectral line in a H–atom is in the order of  (21)<(31)(41), where numbers represent principal quantum numbers

d

An electron with non-zero kinetic energy at infinite distance from the proton, releases more than 13.6 eV when hydrogen atom is formed in its ground state 

answer is A, D.

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Detailed Solution

(a) The difference in angular momentum associated with the electron present in consecutive orbits of unipositive helium ion is h2π
(b) Energy difference between any two energy levels of electron in hydrogen atom does not chnage if potential energy of electron is assigned non-zero value at infinite distance from the nucleus
(c) Frequency of emission spectral line in a H–atom is in the order of  (21)<(31)<(41), where numbers represent principal quantum numbers
(d) An electron with non-zero kinetic energy at infinite distance from the proton, releases more than 13.6 eV when hydrogen atom is formed in ground state

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