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Q.

Which of the following is/are “not correct” for CH3OH+CH3COOH mixture Solution?
1. ΔHmix<0
2. Does not obey Raoult’s law
3. ΔHmix>0
4. An example of ideal solution. 
 

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a

1,3 only

b

3,4 only

c

1,4 only

d

1,2,3 only

answer is A.

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Detailed Solution

In CH3OH  and  CH3COOH   
Mixture solution, A-A and B-B Interactions are weaker than  A-B interactions. It leads to increase in vapour pressure and  positive deviation Raoult’s law.  For solutions showing positive  deviation from Raoult’s law. 
ΔHmix>0andΔVmix>0 
Thus, 1 and 4 are incorrect.
 

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