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Q.

Which of the following is arranged in the order of increasing radius in aqueous solution?

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a

Cs+ < Rb+ < K+ < Na+ < Li+

b

Li+ < K+ < Na+ < Rb+ < Cs+

c

Li+ < Na+ < K+ < Rb+ < Cs+

d

Rb+ < Na+ < Li+ < Cs+ < K+

answer is A.

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Detailed Solution

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The alkali metal ions are highly hydrated. The smaller the size of the ion, the greater is the degree of hydration. Thus, Li+ ion gets much more hydrated than Na+ ion which in turn is more hydrated than K+ ion and so on. The extent of hydration decreases down the group.

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Which of the following is arranged in the order of increasing radius in aqueous solution?