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Q.

Which of the following is correct comparison of rate of haloform reaction with various halogens?

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a

$r_{C l_{2}} \approx r_{B r_{2}} \approx r_{I_{2}}$

b

$r_{B r_{2}} > r_{C l_{2}} > r_{I_{2}}$

c

$r_{C l_{2}} > r_{B r_{2}} > r_{I_{2}}$

d

$r_{I_{2}} > r_{B r_{2}} > r_{C l_{2}}$

answer is D.

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Detailed Solution

Base abstracts acidic hydrogen and then attack of the carbanion on halogen will occur.

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