Q.

Which of the following is correct regarding chlorination of methane in the presence of sunlight

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a

Involves the formation of carbanion

b

Gives only one type of product

c

Involves the formation of carbocation 

d

Involves the formation of carbon free radical  

answer is C.

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Detailed Solution

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The mechanism involves a chain reaction. During a chain reaction, for every reactive species you start off with, a new one is generated at the end - and this keeps the process going. The over-all process is known as free radical substitution, or as a free radical chain reaction.

  • Chain initiation: The chain is initiated (started) by UV light breaking a chlorine molecule into free radicals.
  • Cl2hv2Cl·
  • Chain propagation reactions : These are the reactions which keep the chain going.
  • Question Image
  • Chain termination reactions: These are reactions which remove free radicals from the system without replacing them by new ones.Question Image
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