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Q.

Which of the following is diamagnetic ?

 

 

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a

[Fe(CO)5] 

b

[Fe(CN)6]3-

c

[Cr(NH3)6]3+

d

 [Cr(H2O)6]3+

answer is B.

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Detailed Solution

[Fe(CN)6]3- is more diamagnetic.

CN- =  Strong field ligand, so in d orbital, it will pair up the electrons.

The crystal structure of [Fe(CN)6]3- is 

[Fe(CN)6]3-H2O

The CN-  ligand creates a strong field (since it's a strong field ligand), and the d orbital of the Fe atom will pair up with its partner because of this.

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