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Which of the following is diamagnetic

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[Fe(CO)₅]

[Fe(CN)₆]^3–

[Cr(NH₃)₆]³⁺

[Cr(H₂O)₆]³⁺

answer is A.

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Detailed Solution

Oxidation state of Fe in [Fe(CO)₅] is zero and all outer electrons gets paired when CO (strong ligand) approaches. Therefore, [Fe(CO)₅] is diamagnetic.

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