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Q.

Which of the following is incorrect?

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a

Red ‘P’ is obtained by heating white ‘P’ at 573K in an inert atmosphere for several days

b

αblack phosphorous is formed when red ‘P’ is heated in a sealed tube at 803 K.

c

βblack ‘P’ is prepared by heating white ‘P’ at 473 K under pressure

d

When red ‘P’ is heated under high pressure, white ‘P’ is obtained.

answer is D.

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Detailed Solution

When red phosphorus is heated under high pressure, a series of phases of black phosphorus is formed.

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