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Q.

Which of the following is incorrect match

 HybridisationGeometry                                Orbital use
1sp3dTrigonal bipyramidals+px+py+pz+dz2
2sp3d3Pentagonal bipyramidals+px+py+pz+dx2y2+dz2+dxy
3sp3d2distorted octahedrals+px+py+pz+dx2y2+dz2
4sp3Tetrahedrals+px+py+pz

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a

2

b

1

c

3

d

4

answer is C.

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Detailed Solution

sp3d2  shows regular octahedral, and not distorted

in pentagonal bipyramidal s ,px, py, dxy and  dx2-y2 are in xy plane and pz and dz2 perpendicular to it.

So the d orbitals being used are dxy ,dx2-y2 ,dz2

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