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Q.

Which of the following is incorrect statement?

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a

SnF4 is ionic in nature

b

GeX4(X=F,Cl,Br,I) is more stable than GeX2.

c

SiCl4 is easily hydrolysed.

d

PbF4 iscovalentinnature

answer is B.

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Detailed Solution

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PbF4 is not covalent in nature. According to Fajan’s rule, ‘Pb‘ has large cations and ‘F‘ has small anion. So, PbF4 is of ionic nature.
(1) According to Fajan’s rule, ‘Sn+4‘ has large cation and small anion which form ionic compounds. SnF4 is of ionic nature.
(3) The vacant d-orbitals of Si can coordinate with water moleculues and, hence, SiCl4 is hydrolysed by water.
(4) Stable oxidation state of Ge is +4.

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