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Q.

Which of the following is industrially prepared by passing ethylene into hypochlorous acid followed by sodium bicarbonate .

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a

Ethylene dinitrate

b

Ethylene glycol

c

Ethylene oxide

d

Ethane

answer is D.

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Detailed Solution

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Industrial Preparation of Ethanol

Step 1: Starting Material

Ethylene (CH2=CH2) is reacted with hypochlorous acid (HOCl).

Step 2: Formation of Chlorohydrin

CH2=CH2 + HOCl → CH2Cl–CH2OH

This forms 2-chloroethanol (chlorohydrin).

Step 3: Conversion to Ethanol

CH2Cl–CH2OH + NaHCO3 → CH3–CH2OH

The chlorine atom is replaced by –OH to give ethanol.

Industrial preparation of ethanol from ethylene uses HOCl and NaHCO3.

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