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Q.

Which of the following is major product in the reaction of anisole with CH3Cl/Anhyd. AlCl3 in Cs2?

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a

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b

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c

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d

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answer is C.

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Detailed Solution

Reaction of Anisole with CH₃Cl

Reaction:

O–CH₃ (Anisole) + CH₃–Cl AlCl₃, Δ → O–CH₃ (Mirror) + O–CH₃ (CH₃, Major)

  • Reactant: Anisole (O–CH₃)
  • Reagent: CH₃Cl, AlCl₃
  • Products:
    • Mirror-substituted product (O–CH₃)
    • Major ortho-substituted product (O–CH₃ with CH₃)
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