Q.

Which of the following is methanide?

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a

CaC2

b

Mg2C3

c

Be2C

d

SrC2

answer is A.

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Detailed Solution

Methanides are ionic carbides that contains discreate carbon atoms in the form of C4- and given methane on hydrolysis.

Hydrolysis of Be2C is:

Be2C+4H2O2Be(OH)2+CH4

Hydrolysis of CaC2 is:

CaC2+2H2OCa(OH)2+C2H2

Hydrolysis of SrC2 is:

SrC2+2H2OSr(OH)2+C2H2

Hydrolysis of Mg2C3 is:

Mg2C3+4H2O2Mg(OH)2+HCC-CH3

Hence, Be2C is a methanide.

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Which of the following is methanide?