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Q.

 Which of the following is most soluble in water?

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a

Be3(PO4)2 (Ksp = 6 × 10–39)

b

ZnS (Ksp = 7 × 10–16)

c

Ag3PO4 (Ksp = 1.8 × 10–18)

d

Fe(OH)3 (Ksp = 6 × 10–38)

answer is D.

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Detailed Solution

Ag3PO4[s]Ag3PO4[aq]3Ag+3S[aq]+PO4S-3[aq]

Ksp=(3S)3×S

⇒ 1.8 x 10-18 = 27 x S4

⇒ 20 x 10-16 = 3 x S4

Solubility, S will be of the order of 10-4 which is the largest among other option.

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