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Q.

Which of the following is most stable ?

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a

Sn2+

b

Ge2+

c

Si2+

d

Pb2+

answer is D.

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Detailed Solution

IV A group elements
Common oxidation state is : "+4"
C shows :- +4 -4
Si:- +4 [Stable]
 

Ge,Sn:+2,+4Stable Pb: +2Stable,+4


→ For Ge,Sn +4 is stable oxidation state hence in +2 oxidation state they acts as reducing agents
→ Where as for Pb +2 oxidation state is state [due to inert pair effect] hence in +4 oxidation state Pb acts as oxidising agent
→ Higher oxidation state is due to involvement of ns and np electron
i.e., 

Question Image


Lower oxidation state is due to involvement of only np electron
i.e., ns2 np(2) ⇒ +2
Higher oxidation state stability decreases from top to bottom
 

Question Image

 


Lower oxidation state stability increases from top to bottom
Ge+2 < Sn+2 < Pb+2 Stability order

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