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Which of the following is non-conducting?

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${CoCl}_{3} \cdot 6 {NH}_{3}$

${CoCl}_{3} \cdot 5 {NH}_{3}$

${CoCl}_{8} \cdot 4 {NH}_{3}$

${CoCl}_{3} \cdot 3 {NH}_{3}$

answer is D.

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Detailed Solution

${CoCl}_{3} \cdot 3 {NH}_{3}$ is not conducting because, like the octahedral complex, it does not produce any ions.

However, some complexes produce at least one ion, making them conductors.

(One complex + One chloride) $C o C l_{3} \cdot 4 N H_{3}$ produces two ions.

One complex plus two chlorides are produced when $C o C l_{3} \cdot 5 N H_{3}$ is combined.

Thus, the option D is correct.

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